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1,4 butynediol malosi sili oloa
CAS:110-65-6
O mea tau vaila'au o le butynediol: tioata orthorhombic pa'epa'e.Liu liusuavai 58 ℃, vevela 238 ℃, 145 ℃ (2KPa), moli moli 152 ℃, fa'asino fa'asino 1.450.Solu i le vai, vaifofo acid, ethanol ma acetone, soluble teisi i chloroform, le mafai ona solu i benzene ma eter.
Faʻaaogaina: butynediol e mafai ona faʻaaogaina e gaosia ai le butene glycol, butynediol, n-butanol, dihydrofuran, tetrahydrofuran γ- O se faasologa o mea taua faʻaletino e pei ole butyrolactone ma pyrrolidone e mafai ona faʻaogaina atili e gaosia ai palasitisi faʻapipiʻi, filo synthetic (nylon-4), pa'u fa'akomepiuta, vaila'au, vaila'au fa'atosina, solvents (N-methyl pyrrolidone) ma fa'asao.Butynediol lava ia o se solvent lelei ma e faʻaaogaina e fai ma faʻamalamalamaga i le eletise eletise.
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Samasama lanu samasama e sili ona oona vai 1,4-butynediol
1,4-butynediol malo, fua fa'a-kemikolo C4H6O2, tioata orthorhombic pa'epa'e.Solu i le vai, acid, ethanol ma acetone, le mafai ona solu i benzene ma eter.E mafai ona faʻafefe ai le mucous membrane, paʻu ma le pito i luga o le manava o mata.I alamanuia, 1,4-butynediol malo e masani lava ona saunia e le Reppe auala, catalyzed e butynediol copper po o le kopa bismuth catalyst, ma saunia e ala i le tali atu o le acetylene ma formaldehyde i lalo o le mamafa (1 ~ 20 pa) ma le vevela (110 ~ 112 ° C) .O le butynediol crude e maua e ala i le tali atu, ma o le oloa maeʻa e maua e ala i le faʻamalosi ma le faʻamamaina.
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3-chloropropyne e leai ni lanu e sili ona oona e mu
O le 3-chloropropyne o se mea faʻapipiʻi faʻapipiʻi faʻatasi ma le faʻatulagaina o le ch ≡ cch2cl.O foliga vaaia e leai se lanu e mumu.Liu liusuavai -78 ℃, fa'avela 57 ℃ (65 ℃), va'aiga va'aiga 1.0297, fa'asino fa'asino 1.4320.Fa'ailoga moli 32.2-35 ℃, toetoe lava a le mafai ona solu i le vai ma le glycerol, fa'afefiloi ma le benzene, carbon tetrachloride, ethanol, ethylene glycol, eter ma ethyl acetate.E maua e ala i le tali atu o le propargyl alcohol ma le phosphorus trichloride.Fa'aaogaina e fai ma mea fa'avauvau i le fa'aogaina o meaola.
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Suavai sili ona oona oloa sili atu le propargyl alcoho
Suavai e le lanu, fe'avea'i ma le manogi manogi.E faigofie ona liu samasama pe a tuʻu mo se taimi umi, aemaise lava pe a faʻaalia i le malamalama.E fefiloi ma vai, benzene, chloroform, 1,2-dichloroethane, eter, ethanol, acetone, dioxane, tetrahydrofuran ma pyridine, soluble vaega i le carbon tetrachloride, ae le mafai ona solu i aliphatic hydrocarbons.
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Fa'agasologa ole gaosiga ole 'ava mālosi ole Propargyl ma au'ili'iliga ole maketi
O le Propargyl alcohol (PA), e masani ona ta'ua o le 2-propargyl alcohol-1-ol, o se vai e leai ni lanu, e feololo ma se manogi manogi o lau lau.O le mamafa o le 0.9485g/cm3, liusuavai: -50 ℃, vevela: 115 ℃, moli moli: 36 ℃, mu, pa: soluble i le vai, chloroform, dichloroethane, methanol, ethanol, ethyl ether, dioxane, tetrahydrofuran, pyridine, solute teisi i le carbon tetrachloride, le mafai ona solu i aliphatic hydrocarbon.Propargyl alcohol o se vailaʻau mataʻutia taua, faʻaaogaina lautele i vailaʻau, vailaʻau vailaʻau, eletise eletise, vailaau faʻasaina, sila, suauu ma isi fanua.
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Faʻaaogaina o le butanediol i mea teuteu
Butanediol, tele acetylene ma formaldehyde e fai ma mea mata.E faʻaaogaina e fai ma faʻalautele filifili mo le gaosiga o le polybutylene terephthalate ma le polyurethane, ma o se mea taua tele mo le tetrahydrofuran, γ-butyrolactone, vailaʻau ma le faʻaogaina o meaola.Talu ai o le polybutylene terephthalate o se ituaiga polyester ma mea lelei, o le manaʻoga mo palasitika inisinia ua faʻateleina vave.
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Ose vaila'au e sili ona oona ile falesu'esu'e - propargyl alcohol
Propargyl Alcohol, molecular formula C3H4O, molecular weight 56. Suavai manino e leai ni lanu, fe'avea'i ma manogi manogi, o'ona, afaina tele i le pa'u ma mata.O se mea fa'avauvau i le fa'aogaina o meaola.Fa'aaogaina mo le tu'ufa'atasiga o vaila'au antibacterial ma anti-inflammatory sulfadiazine;A maeʻa le faʻamaʻiina o vaega, e mafai e le propylene alcohol ona maua ai le resini, ma a maeʻa le faʻamaina atoatoa, e mafai ona faʻaaogaina le n-propanol e fai ma mea mata o le ethambutol fualaau faʻamaʻi faʻamaʻi, faʻapea foʻi ma isi vailaʻau ma vailaʻau.E mafai ona taofiofia le acid i le uʻamea, kopa ma le nickel ma isi metala pala, faʻaaogaina e pei o le aveeseina o le ele.Fa'aaoga lautele i le suau'u suau'u.E mafai foi ona faʻaaogaina e fai ma solvent, stabilizer o chlorinated hydrocarbons, herbicide ma insecticide.E mafai ona faʻaaogaina mo le gaosiga o le acrylic acid, acrolein, 2-aminopyrimidine, γ-picauline, vitamini A, stabilizer, inhibitor corrosion ma isi.
Isi igoa: propargyl alcohol, 2-propargyl – 1-alcohol, 2-propargyl alcohol, propargyl alcohol acetylene methanol.
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Propargyl o le a polymerize ma pa
O le fa'agasologa muamua e fa'avae i luga o le ava malosi propargyl e pei o le solvent, KOH e pei o le fa'avae, fa'avevela tali e maua ai le fa'amoemoe.Reaction e aunoa ma solvent dilution tulaga o le a faaitiitia eleelea, o le tali e mama.
Mafaufau i le mafai ona fa'apipi'iina fa'apea ma le pala o alkynes fa'amau, o le Amgen's Hazard Evaluation Lab (HEL) na laa i totonu e fa'atino su'esu'ega mo le saogalemu ma fesoasoani i le fa'avasegaina o le fa'agasologa a'o le'i fa'ateleina i le 2 lita o le tali.
O le suʻega DSC o loʻo faʻaalia ai o le tali e amata ona pala i le 100 °C ma faʻamalolo 3667 J / g le malosi, aʻo faʻatasi le propargyl alcohol ma KOH, e ui ina pa'ū le malosi i le 2433 J / g, ae o le vevela o le decomposition e pa'ū foi i le 85 °C, ma ole vevela ole faagasologa e latalata tele ile 60 °C, e sili atu le lamatiaga o le saogalemu.
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1,4-butanediol (BDO) ma lona tapenaga ole PBAT palasitika e mafai ona pala
1, 4-butanediol (BDO);O le PBAT o se palasitika e mafai ona fa'a'ele'elea, o se copolymer o le butanediol adipate ma le butanediol terephthalate.E iai uiga ole PBA (polyadipate-1, 4-butanediol ester diol) ma le PBT (polybutanediol terephthalate).E lelei ductility ma elongation i le motusia, faʻapea foʻi ma le vevela lelei ma le faʻatinoga o aʻafiaga.E le gata i lea, o loʻo i ai le biodegradability sili ona lelei ma o se tasi o mea sili ona lauiloa i le suʻesuʻeina o palasitika biodegradable ma sili ona lelei le faʻaogaina i le maketi.
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Gaosiga ole 1,4-butanediol (BDO) ile maleic anhydride method
E lua auala autu mo le gaosiga o le BDO e maleic anhydride.O le tasi o le faiga tuusao hydrogenation o maleic anhydride atiina ae e Mitsubishi Petrochemical ma Mitsubishi Chemical i Iapani i le 1970s, lea e iloga i le gaosiga tutusa o BDO, THF ma GBL i le hydrogenation faagasologa o maleic anhydride.O oloa o fatuga eseese e mafai ona maua e ala i le fetuunaiga o tulaga o le faagasologa.O le isi o le gas esterification hydrogenation process o maleic anhydride na atiina ae e le UCC Company ma Davey Process Technology Company i Peretania, lea e atiina ae mai le tekonolosi carbonyl synthesis maualalo.I le 1988, na maeʻa ai le toe iloiloga o le faʻagasologa o le faagasologa ma na faʻatulagaina le mamanu o fale gaosimea.I le 1989, NA ILIUINA LE TEKNOLOGI I DongSANG CHEMICAL COMPANY O Korea MA DONGGU CHEMICCAL COMPANY O Iapani E FAUSI SE 20,000-TON/year 1, 4-BUtanEDIOL INDUSTRIAL production PLANT.
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1, 4-butanediol meatotino
1, 4-butanediol
Fa'aigoa: 1, 4-dihydroxybutane.
Faapuupuuga: BDO,BD,BG.
Igoa Igilisi: 1, 4-Butanediol;1, 4 - butylene glycol;1, 4 – dihydroxybutane.
Ole fua ole mole ole C4H10O2 ma ole mamafa ole mole ole 90.12.Ole numera CAS ole 110-63-4, ma ole numera EINECS ole 203-785-6.
Fua fa'atatau: HOCH2CH2CH2CH2OH.
Oloa
Faʻapitoa i le gaosiga o le propargyl alcohol, 1,4 butynediol ma le 3-chloropropyne
